These investigations would suggest the addition of these anions to have an inhibiting effect in pitting of stainless steels. Oct 08, 20 if the atmosphere contains halides this can leave any stainless steel susceptible to chloride stress corrosion cracking ciscc. It requires a susceptible material and, depending on the material, sufficient levels of. Pitting corrosion is avoided by making sure that stainless steel does not come into prolonged contact with harmful chemicals or by. Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl.
Austenitic stainless steel may be susceptible to chloride stress corrosion cracking cscc. Elevated stress susceptible material corrosive environment surface contamination by atmospheric chlorides sufficient humidity epri has a multiyear project to. Stress corrosion cracking of an austenitic stainless steel in nitritecontaining chloride solutions r. In this study the influence of operating conditions such as chloride concentration, temperature on stress corrosion cracking of austenitic stainless steel will be investigated. Mechanism of chloride stress corrosion cracking of austenitic. The boiling magnesium chloride test cracks materials with the nickel levels found in relatively resistant austenitic and duplex stainless steels, thus. Chloride stress corrosion cracking in austenitic stainless. Type 304 stainless steel electrodes were employed, with complementary.
There is a synergistic relationship between dissolved oxygen and the chloride level. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. The 300 series stainless steels can also experience chloride stress corrosion cracking in contact with ammonium chloride deposits. Addition of nitrite to the chloride solution, which is reported to have inhibitive influence on corrosion of stainless. Environmental factors concentration nh 3, hcl, h 2 0 or amine salts, temperature and water availability are the critical factors. Chloride corrosion can be caused by the combination of insulation containing leachable chlorides with the 300 series austeniticstainlesssteel surfaces, when moisture is present and temperatures are above 140 o f. Stress corrosion cracking of an austenitic stainless steel. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. If the atmosphere contains halides this can leave any stainless steel susceptible to chloride stress corrosion cracking ciscc. What is temperature it is more important than concentration of chloride and anything higher than room temperature higher is worse. Certain austenitic stainless steels and aluminium alloys crack in the presence of chlorides.
Significant scc could affect the ability of the spent fuel storage canisters to perform their confinement function during the initial license or license renewal storage periods. Mechanism of chloride stress corrosion cracking of. Astm g123 002015 standard test method for evaluating. Ordinarily we would specify 316l stainless steel to limit the corrosion, but i was asked if we could instead specify carbon steel pipe with a corrosion allowance. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Pdf chloride induced stress corrosion cracking of type. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. For example, chloride stress corrosion cracking of austenitic stainless steels has been experienced in hotwater jackets around chocolate pipes that is to say, pipes carrying molten chocolate in the food industry. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. In austenitic stainless steel, the main forms of corrosion are pitting and stress corrosion cracking caused by chlorides. Chloride scc is clearly the bane of austenitic stainless steels and one of the main reasons they are not the miracle cure for many corrosion problems. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f.
Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Stress corrosion cracking facts and how to reduce the risk. They are the austenitic, ferritic, and duplex austeniticferritic families. The effect of salt loading on chlorideinduced stress. When a process is inadvertently contaminated with chlorides by unsuspecting people. Type 304 steel is a metastable austenite and is highly susceptible to martensite formation 14. The 304 and 304l 188 stainless steel alloys have been utilized very successfully in fresh waters containing low levels of chloride ion of up to 100 ppm. Stainless steel grades 600 series this series of stainless steels grade is commonly referred to as precipitation hardening stainless steels. Stress corrosion cracking is the cracking of a susceptible metal under the mixed. In general, this test method is more useful for stainless steels than the boiling magnesium chloride test of practice g36.
For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Three general classifications are used to identify stainless steels. Electrochemical studies were made in aqueous licl, mgcl 2, and mgbr 2 solutions and in zncl 2 kcl molten salt to clarify the corrosion reactions related to stress corrosion cracking scc of austenitic stainless steel and to better define environmental variables critical to the occurrence of chloride scc. High residual or applied stress, temperature above 6571c 150160f and chlorides increase the likelihood of cscc. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. While no stainless steel can be completely immune, swageloks alloy 316 stainless steel fittings have performed exceptionally well in testing. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2 at above about 100c. Three underlying factors must be present to cause scc.
Lean duple stainless steel product description ak steel nitronic 19d stainless steel is a lean duplex stainless steel with a mixed ferrite and austenite structure. Chloride stress corrosion cracking inspectioneering. Chloride stress corrosion cracking and 316 stainless steel. Chloride induced stress corrosion cracking ciscc of stainless steel reactor components has occurred when three elements are all present. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. Susceptibility assessment criteria for chlorideinduced. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride solution. Chloride stress corrosion cracking is a localized corrosion mechanism like pitting and crevice corrosion. Introduction stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries.
Both of type 304 and type 316 stainless steels showed quite similar. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Chlorine in contact with water and as a dissolved gas, sometimes found in water treatment applications, is potentially aggressive to stainless steels. A maximum temperature of 60 deg c is given presumably to avoid stress corrosion cracking but with regard to chloride concentration limits it says any combination of chloride. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Stress corrosion cracking of sensitized type 304 stainless. Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur.
High performance stainless steels nickel institute. The chloride concentration in the solution leads to localized pitting or crevice corrosion nucleation. Stress corrosion cracking scc stainless steel test specimens were simultaneously subjected to mechanical stress and exposed to 8%wt. Chloride corrosion of carbon steel pipe engineering. Consequently, intergranular cracking for these austenitic stainless steels in the boiling magnesium chloride solution revealed more brittle nature in comparison with transgranular cracking. Chloride corrosion of carbon steel pipe engineering stack. Chloride induced stress corrosion cracking of stainless steel. Singh raman 1, and wai hoong siew 2 1 department of mechanical and aerospace engineering, monash university, melbourne, victoria 3800, australia 2 mechanical engineer, ibm australia 60 city road melbourne, victoria 3006 australia. This limits the usefulness of austenitic stainless steel for containing water with higher than a few ppm content of chlorides at temperatures above 50c. Most people have seen the spiderwebbed and lightening array type network of highly branched cracks that is common with chloride cracking of sss. This level of chloride is considered to be the limit for the 188 alloys, particularly if crevices are present. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media.
Cracking from corrosion under insulation cui which contains small amounts. Pitting corrosion the passive layer on stainless steel can be attacked by certain chemical species. Mild steel cracks in the presence of alkali boiler cracking and nitrates. Chloride stress corrosion cracking in austenitic stainless steel.
Addition of oxygen in autoclaves promoted the tendency to stress corrosion cracking. Oct 21, 2019 chloride stress corrosion cracking is a localized corrosion mechanism like pitting and crevice corrosion. Selection of stainless steels for handling chlorine cl2. What forms of corrosion can occur in stainless steels. There are three primary classifications within the highperformance stainless steels. While intergranular stress cracking is commonly observed in sensitized parts of the stainless steel structure at ambient to moderate. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. The standard 304304l and 316316l grades are most susceptible. The use of 316l would be more resistant to crevice corrosion attack. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and.
Chloridechlorine levels and stainless steel alloy selection. The hsl research report 902 reference 1 covers the susceptibility of stainless steel to ciscc in some detail and links to. Chloride induced stress corrosion cracking of stainless. So instead of the typical schedule 40 pipe, could i realistically use schedule 80 or 120 etc. Stress corrosion cracking of new 2001 leanduplex stainless. This alloy provides high yield strength, good drawing and welding characteristics, excellent chloride stress corrosion cracking resistance, and high cyclic oxidation resistance. Stress corrosion cracking of an austenitic stainless steel in.
Reference is often made to stainless steel in the singular sense as if it were one material. What is the maximum chloride in ppm that can be allowed in. Pdf stress corrosion cracking of austenitic stainless. Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to cscc. Stress corrosion cracking facts and how to reduce the. Although no stainless steel grade is totally immune. I am specifying pipes for a water system with 500 ppm chloride in solution. Failure analysis of corrosion on stainless steel fasteners.
The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. The combination of tensile stress and a specific corrosive environment can crack stainless steels. The hsl research report 902 reference 1 covers the susceptibility of stainless steel to ciscc in some detail and links to other research papers and published documents. Intergranular stress corrosion cracking of welded steel twi. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0.
Chloride stress corrosion cracking cscc in stainless steel. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks.
Methods of minimizing chloride stress corrosion cracking. Prevention of chloride stress corrosion cracking cscc in austenitic stainless steel material for closed loop waterglycol mixture are as follows elimination of oxygen is an effective measure to prevent cscc in neutral and alkaline solutions. The use of a duplex stainless steel with molybdenum such as stainless alloys 2205 or 2507 would resist crevice corrosion and stress corrosion cracking. The stainless steels in each family have general similarities, but there is also a wide range of corrosion resistance and other characteristics. So instead of the typical schedule 40 pipe, could i. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and carbonatebicarbonate solutions. On the stress corrosion cracking and hydrogen embrittlement.
This mode of attack is termed stress corrosion cracking scc. Concentration of the chloride ion usually results from the evaporation of rain water,or of water used to fight fires, or of process. These steels can be heat treated to high strength levels. Complete removal of oxygen by means of non scaling oxygen scavengers e. Higher levels of chloride might cause crevice corrosion and pitting. Cscc can attack highly resistant austenitic stainless steel. Pdf chloride induced stress corrosion cracking of type 304. Chloride cracking of 300 series stainless steels continues to occur in a number of places, including. They are subject to crevice corrosion and pitting in chloride containing environments and are also subject. Stress corrosion cracking scc is a common issue with many specialty alloys. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries.
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